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Application of different fractionation techniques for structure determination of ICP
Dostálová, Dagmar ; Kratochvíla,, Jan (referee) ; Buráň,, Zdeněk (advisor)
Impact E/P copolymer (ICP) is produced using gas-phase polymerization catalysed by Ziegler-Natta catalysts. This material with its excellent mechanical properties is used in many industries, for example in automotive industry to produce bumpers or instrument panels. Its properties depend on chemical structure which was analysed using DSC, 13C NMR and GPC. It was used 6 different samples of ICP for studies, the chosen samples have different ratio between ethylene and propylene in their copolymer phase. The samples were fractionated using preparative TREF and solvent extraction to obtain fractions, which composition depends on elution temperature. Obtained fractions and original samples were subsequently analysed using above-mentioned methods.
Application of different fractionation techniques for structure determination of ICP
Dostálová, Dagmar ; Kratochvíla,, Jan (referee) ; Buráň,, Zdeněk (advisor)
Impact E/P copolymer (ICP) is produced using gas-phase polymerization catalysed by Ziegler-Natta catalysts. This material with its excellent mechanical properties is used in many industries, for example in automotive industry to produce bumpers or instrument panels. Its properties depend on chemical structure which was analysed using DSC, 13C NMR and GPC. It was used 6 different samples of ICP for studies, the chosen samples have different ratio between ethylene and propylene in their copolymer phase. The samples were fractionated using preparative TREF and solvent extraction to obtain fractions, which composition depends on elution temperature. Obtained fractions and original samples were subsequently analysed using above-mentioned methods.

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